化学
二甲基硫醚
甲醇
产量(工程)
试剂
硫化物
摩尔比
催化作用
无机化学
氧化物
二甲基二硫化物
硫化钠
有机化学
硫黄
核化学
冶金
材料科学
标识
DOI:10.1134/s1070428011050046
摘要
The synthesis of dimethyl sulfide consists in the reaction of dimethyl disulfide with methanol in the presence of solid catalyst, aluminum γ-oxide. The yield of dimethyl sulfide grows with growing temperature, contact time, and content of methanol in the reaction mixture. At 350–400°C, molar ratio methanol-dimethyldisulfide 2.0–2.5, and total conversion of the reagents the yield of dimethyl sulfide reached 95 mol%.
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