化学
催化作用
钴
异构化
锌
漫反射红外傅里叶变换
分子筛
表征(材料科学)
多相催化
漫反射
硅
无机化学
核化学
光谱学
物理化学
结晶学
有机化学
纳米技术
光催化
物理
光学
量子力学
材料科学
作者
João P. Lourenço,M.F. Ribeiro,F. Ramôa Ribeiro,João Rocha,Barbara Onida,Edoardo Garrone,Z. Gabélica
出处
期刊:Zeolites
[Elsevier]
日期:1997-05-01
卷期号:18 (5-6): 398-407
被引量:22
标识
DOI:10.1016/s0144-2449(97)00028-6
摘要
The experimental conditions leading to the synthesis of pure and highly crystalline AlPO4-40, CoAPO-40, and ZnAPO-40 have been optimized. Although the preparation of these phases is favored by the presence of TMA+ in the synthesis gel, these ions have not been found incorporated in the final AFR structures. All materials have been characterized by powder XRD, t.g./d.s.c, SEM, EDX, 13C, 27AI, and 31P solid-state n.m.r., diffuse reflectance u.v.-vis spectroscopy, FT i.r., and catalytic tests using the m-xylene isomerization as a model reaction. This multitechnique approach provides strong evidence for the framework incorporation of cobalt and zinc. The acid sites generated by the framework insertion of cobalt and zinc are stronger than those generated by the incorporation of silicon.
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