High‐Entropy Engineering of 1D Na 4 Fe 3 (PO 4 ) 2 P 2 O 7 : Unlocking Exceptional Capacity and Ultrahigh Rate Capability for Sodium‐Ion Battery Cathodes

Abstract Na 4 Fe 3 (PO 4 ) 2 P 2 O 7 is thought to be a promising cathode material for sodium‐ion batteries (SIBs) because of its inexpensive cost and quick 3D pathways for sodium ion migration. However, traditional modified methods often result in the formation of electrochemically inactive triphylite NaFePO 4 and low‐capacity NaFeP 2 O 7 , alongside low electronic conductivity, leading to a capacity loss for Na 4 Fe 3 (PO 4 ) 2 P 2 O 7 . Herein, this investigation presents the initial development of an innovative 1D, high‐entropy Na 4 Fe 2.5 (MgCuZnNiCo) 0.1 (PO 4 ) 2 P 2 O 7 (NFPP‐HEES) cathode material tailored for SIBs, utilizing electrostatic spinning technology for the first instance, which exhibits incredible reversible capacity and ultrahigh rate performance. The electrochemical activity of Ni 2+ contributes to the maintenance of high specific capacity in NFPP‐HEES, reaching 127.6 mAh g −1 . Additionally, Zn, Co, Cu, and Mg serve as structural pillars, minimizing the cell volume change of NFPP‐HEES to a remarkable 0.02%. This results in improved rate performance and cycling stability, especially at 50 C, where the capacity remains at 90 mAh g −1 . The synergetic effect of high‐entropy ions significantly narrows the bandgap of NFPP‐HEES and diminishes the Na + diffusion energy barrier, thereby substantially improving the kinetic performance. This research presents a novel strategy for the advancement of SIBs cathode materials with high capacity and superior rate capability.