Precise assembly/disassembly of homo-type and hetero-type macrocycles with photoresponsive and non-photoresponsive dynamic covalent bonds

enhanced discrimination and hierarchical assembly. Light-induced kinetic locking/unlocking of dynamic bonds further afforded macrocycle-to-macrocycle conversion when needed. Through leveraging controllable covalent connection/disconnection, switchable formation/disintegration of mechanically interlocked catenanes was further accomplished. The results described showcase the potential of photoinduced dynamic covalent chemistry for preparing complex architectures and should set the stage for molecular recognition, dynamic assemblies, synthetic motors, and responsive materials.