Magnesium Oxide-Supported Single Atoms with Fine-Modulated Steric Location for Polymerization Transfer Removal of Water Pollutants

-band center of the Cu atoms. The optimized catalyst achieved complete, rapid removal of phenolic compounds from water via nearly 100% PT pathway, accompanied by high oxidant utilization efficiency surpassing most state-of-the-art SACs. Moreover, it showed excellent structural stability and environmental robustness and was successfully used for the treatment of lake water and industrial coking wastewater. The adaptability of the spatial engineering strategy to other MgO-supported single atoms, including Fe, Co, and Ni SACs, was also demonstrated. Our work lays a foundation for further advancing SACs-based advanced oxidation technologies toward sustainable water purification applications.