Structural and electrochemical progress of O3-type layered oxide cathodes for Na-ion batteries

Sodium-ion batteries (SIBs) have attracted great attention being the most promising sustainable energy technology owing to their competitive energy density, great safety and considerable low-cost merits. Nevertheless, the commercialization process of SIBs is still sluggish because of the difficulty in developing high-performance battery materials, especially the cathode materials. The discovery of layered transition metal oxides as the cathode materials of SIBs brings infinite possibilities for practical battery production. Thereinto, the O3-type layered transition metal oxides exhibit attractive advantages in terms of energy density benefiting from their higher sodium content compared to other kinds of layered transition metal oxides. Enormous research studies have largely put forward their progress and explored a wide range of performance improvement approaches from the morphology, coating, doping, phase structure and redox aspects. However, the progress is scattered and has not logically evolved, which is not beneficial for the further development of more advanced cathode materials. Therefore, our work aims to comprehensively review, classify and highlight the most recent advances in O3-type layered transition metal oxides for SIBs, so as to scientifically cognize their progress and remaining challenges and provide reasonable improvement ideas and routes for next-generation high-performance cathode materials.