双金属片
双金属
电催化剂
催化作用
碳纳米管
塔菲尔方程
材料科学
化学工程
无机化学
析氧
金属
纳米技术
化学
电极
有机化学
电化学
冶金
复合材料
工程类
物理化学
作者
Yiping Mo,Shanshan Liu,Guilin Liu,Gangqiang Wang,Wangyang Lü
出处
期刊:ChemNanoMat
[Wiley]
日期:2022-09-20
卷期号:8 (11)
被引量:4
标识
DOI:10.1002/cnma.202200330
摘要
Abstract The preparation and research of high‐efficient bifunctional non‐noble metal electrocatalyst is the key to bolster the further development of Zinc−air batteries. Herein, we account the fabrication of a kind of Fe/Co/N‐codoped catalysts (CoFe‐COF bpda /CNT−X) derived from bimetallic COFs/carbon nanotube composites toward both oxygen reduction reaction (ORR) and oxygen evolution reaction (OER). The bipyridine were optioned and indited in the COFs to anchor metal ions (Fe), which can effectively keep back the migration and aggregation of metal ions during pyrolysis. The obtained CoFe‐COF bpda /CNT‐700 exhibits higher ORR catalytic performance, with half‐wave potential reaches 0.862 V and the limiting current density is 5.12 mA cm −2 in 0.1 M KOH solution. For OER, the CoFe‐COF bpda /CNT‐700 at the current density of 10 mA cm −2 is as low as 1.67 V and smaller Tafel slope compared to most oxygen electrocatalysts in 0.1 M KOH solution. Furthermore, the application of CoFe‐COF bpda /CNT‐700 as the air cathode in Zinc−air battery displays outstanding property and enhanced cycling stability compared with Pt/C−IrO 2 .
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