电池(电)
阳极
电解质
阴极
插层(化学)
钾离子电池
石墨
材料科学
化学
无机化学
化学工程
电极
复合材料
磷酸钒锂电池
工程类
物理化学
功率(物理)
物理
量子力学
作者
Zhiming Zhao,Yongjiu Lei,Lin Shi,Zhengnan Tian,Mohamed N. Hedhili,Yasir Khan,Husam N. Alshareef
标识
DOI:10.1002/anie.202212941
摘要
The popular metal-ion batteries (MIBs) suffer from environmental and economic issues because of their heavy dependency on nonrenewable metals. Here, we propose a metal-free ammonium (NH4+ )-based dual-ion battery with a record-breaking operation voltage of 2.75 V. The working mechanism of this sustainable battery involves the reversible anion (PF6- ) intercalation chemistry in graphite cathode and NH4+ intercalation behavior in PTCDI (3,4,9,10-perylenetetracarboxylic diimide) anode. This new battery configuration successfully circumvented the reduction susceptibility of NH4+ and the lack of mature NH4+ -rich cathodes for NH4+ ion batteries (AIBs). The customized organic NH4+ electrolyte endows the graphite||PTCDI full battery with durable longevity (over 1000 cycles) and a high energy density (200 Wh kg-1 ). We show that the development of AIBs should be high-voltage-oriented while circumventing low operation potential to avoid NH4+ reduction.
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