Tackling the Challenges of Aqueous Zn‐Ion Batteries via Polymer‐Derived Strategies

Abstract Zn‐ion batteries (ZIBs) have gathered unprecedented interest recently benefiting from their intrinsic safety, affordability, and environmental benignity. Nevertheless, their practical implementation is hampered by low rate performance, inferior Zn 2+ diffusion kinetics, and undesired parasitic reactions. Innovative solutions are put forth to address these issues by optimizing the electrodes, separators, electrolytes, and interfaces. Remarkably, polymers with inherent properties of low‐density, high processability, structural flexibility, and superior stability show great promising in tackling the challenges. Herein, the recent progress in the synthesis and customization of functional polymers in aqueous ZIBs is outlined. The recent implementations of polymers into each component are summarized, with a focus on the inherent mechanisms underlying their unique functions. The challenges of incorporating polymers into practical ZIBs are also discussed and possible solutions to circumvent them are proposed. It is hoped that such a deep analysis could accelerate the design of polymer‐derived approaches to boost the performance of ZIBs and other aqueous battery systems as they share similarities in many aspects.