Tailored fabrication of biodegradable polymer/ Fe3O4 doped WO3 nano star-based porous membrane with enhanced photo fentonic activity for environmental remediation

The accelerated development of special-wetting polymeric materials with hierarchical pores for membrane applications is crucial to effectively separating water-soluble and insoluble pollutants, such as oily wastewater, emulsion, organic pollutants, and heavy metals. This pressing environmental and socioeconomic issue requires the implementation of effective remediation technologies. In this study, we successfully fabricated an environmentally friendly membrane with a flexible property by combining biopolymers and magnetic nanohybrids of iron oxide (Fe3O4)-doped tungsten oxide (WO3) through a thermal-induced phase separation process (TIPS). The resulting membrane exhibited a well-defined 3D-interconnected porous network structure when blending poly (ε-caprolactone)/poly (D,L-lactide) (PCL)/(PDLLA) in an 8:2 vol ratio. The Fe3O4@WO3 nanohybrids were synthesized using a hydrothermal process, resulting in a star-shaped morphology from the sea urchin-like WO3 clusters, which showed great potential to efficiently separate water/oil contamination and facilitate visible-light-driven photocatalytic degradation of organic dyes (MB, Rh B, BY, and CR) and photoreduction of hexavalent chromium (Cr (VI)). The obtained PCL/PDLLA/Fe3O4@WO3 nanocomposite membrane demonstrated hydrophobic properties, showing a water contact angle of 95 ± 2° and an excellent oil adsorption capacity of ∼4–4.5 g/g without fouling. The interconnected porous structure of the composite membrane enabled the efficient separation of emulsions (≥99.4 %) and achieved a high permeation flux of up to 1524 L m−2 h−1 under gravity separation. Overall, we obtained a novel high-performance composite material with specialized wetting properties, offering significant potential for effectively removing insoluble and soluble organic contaminants from wastewater.