Simultaneous Improvement of Bendability and Passive Daytime Radiative Cooling Performance in Multilayer Alumina Fiber Membranes

Passive daytime radiative cooling (PDRC) materials require high solar reflectance and high atmospheric window emissivity. However, high solar reflectance achieved by scattering strategies often relies on porous structures, which can compromise the material's mechanical reliability. To address this trade-off, we develop a layered alumina nanofiber membrane (LANM) by dual-nozzle electrospinning with programmed alternating deposition, in which alternating deposition and subsequent removal of alumina precursor layers and sacrificial polyvinyl alcohol (PVA) interlayers generate a continuously layered architecture with periodic interfaces and interlayer air gaps. This interfacial geometric design enables simultaneous regulation of solar-band scattering and bending load transfer within a single alumina system. Because photon flux attenuates with depth, shallow interfaces contribute more strongly than deeper ones; therefore, the micro-layered architecture enhances scattering while maintaining high emissivity in the atmospheric window. In outdoor testing, LANM achieved a maximum sub-ambient temperature reduction of ~5.8 °C, representing a further improvement of about 2.4 °C compared to Monolithic alumina nanofiber (ANM). Moreover, interlayer interfaces induce a multiple-neutral-axis mechanism and segmented stress transfer, thereby improving bending deformability rather than load-bearing strength.