Tunable Pd/C-catalyzed oxidative alkoxycarbonylation/aminocarbonylation of aryl hydrazines with alcohols/inert tertiary amines through C–N bond activation

We report Pd/C-catalyzed oxidative amino- and alkoxycarbonylation of unactivated aryl hydrazines, employing inert tertiary amines as an aminal source and arylhydrazines via oxidative sp 3 and sp 2 C–N bond activation using molecular oxygen as an oxidant.