磷酰胺
化学
催化作用
路易斯酸
苯并呋喃
对映选择合成
组合化学
分子
对称化
立体化学
有机化学
生物化学
寡核苷酸
DNA
作者
Byungjun Kim,Sarah Yunmi Lee
标识
DOI:10.1016/j.checat.2022.06.011
摘要
In a recent issue of Chem , Liu and Feng et al. report a stereodivergent allylation of benzofuran-3( 2H )-one catalyzed by two chiral metal catalysts, a phosphoramidite-Ir complex and an N,N′ -dioxide-ligated Lewis acid, and its application to the selective total synthesis of eight stereoisomers of rocaglaol, one of the flavagline-family bioactive molecules. In a recent issue of Chem , Liu and Feng et al. report a stereodivergent allylation of benzofuran-3( 2H )-one catalyzed by two chiral metal catalysts, a phosphoramidite-Ir complex and an N,N′ -dioxide-ligated Lewis acid, and its application to the selective total synthesis of eight stereoisomers of rocaglaol, one of the flavagline-family bioactive molecules.
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