聚氨酯
纳米复合材料
材料科学
差示扫描量热法
热重分析
傅里叶变换红外光谱
预聚物
肿胀 的
高分子化学
氢键
化学工程
复合材料
化学
有机化学
分子
热力学
物理
工程类
作者
Adel Soleimani,Gity Mir Mohamad Sadeghi
标识
DOI:10.1002/slct.202103978
摘要
Abstract A hybrid thermo‐reversible crosslinking polyurethane nanocomposite containing 0.5, 1, and 2 wt.% of nano‐silica was prepared with three intrinsic self‐healing bonds (reversible covalent bonds supported by intrinsic hydrogen bonds and dangling chains). Owing to the introduction of pseudo‐tannin and polyester diol that could form phenol‐urethane networks and using nano‐silica that causes dangling chains and hydrogen bonds, the prepared polyurethanes are capable of being reversed at 110 °C and rejoin at low temperatures. Thermoset self‐healing polyurethane nanocomposites are prepared from pseudo‐tannin, nano‐silica, and a urethane‐based prepolymer. The investigations of chemical structure, self‐healing behavior, and cross‐link network are carried out by Fourier Transform Infrared Spectroscopy (FTIR), Differential Scanning Calorimetry (DSC) technique, and swelling test. dissociation of phenolic urethane at 110 °C was confirmed by temperature variable FTIR. By swelling test, it was found that the self‐healing polyurethane nanocomposites with 0.5 wt.% of nano‐silica have the most hard‐domain, gel content, and crosslink density in the samples. DSC technique shows that polyurethane samples have two heat transfer transitions (dangling chains and self‐healing). Thermogravimetric analysis (TGA) findings show that nanocomposites decompose at elevated temperatures than neat PU, and the rate of degradation diminishes as silica content increases.
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