期刊:Chemistry of Materials [American Chemical Society] 日期:2010-04-21卷期号:22 (10): 3192-3196被引量:95
标识
DOI:10.1021/cm100290b
摘要
Here, we report the remarkable oxygen intake/release capability of a double perovskite BaYMn 2 O 5+δ . This oxide rapidly stores/releases a large amount of oxygen (>3.7 wt %) at moderate temperatures in a perfectly reversible manner. The oxygen intake/release behaviors of BaYMn 2 O 5+δ are clearly beyond those of any conventional oxides in terms of the magnitude and sharpness of the processes. It also appeared that this oxide exhibits a significant catalytic activity for flameless combustions of hydrocarbons, presumably owing to its oxygen-storage ability.