倾点
纳米复合材料
蜡
抑制剂
材料科学
化学工程
醋酸乙烯酯
成核
针状的
化学
复合材料
有机化学
聚合物
微观结构
共聚物
药理学
工程类
医学
作者
Hailin Yu,Zhengnan Sun,Guolin Jing,Zhiwei Zhen,Yang Liu,Kai Guo
出处
期刊:Energy & Fuels
[American Chemical Society]
日期:2019-05-29
卷期号:33 (7): 6069-6075
被引量:40
标识
DOI:10.1021/acs.energyfuels.9b00689
摘要
Nanocomposite pour point depressants (PPDs) provide a new way to further improve the fluidity of waxy crude oil at low temperatures, which has important application values in pipeline transportation. In this work, the effect of ethylene-vinyl acetate (EVA) doped with magnetic spherical nanoparticles of Fe3O4 (30 nm) on the morphology of wax crystals and the flow behavior of Daqing crude oil was investigated by polarized optical microscopy and rheological testing. The results showed that, compared to the EVA PPD doped with spherical nano-SiO2 (with the same size), the EVA (VA = 28%)/Fe3O4 nanocomposite PPD caused Daqing crude oil to have a more compact and regular wax crystal structure and a weaker gel structure because of the synergistic effect of magnetic materials and heterogeneous nucleation. This study examines the mechanism of nanocomposite PPDs and provides a new perspective for the development of new nanohybrid PPDs.
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