铁氰化物
木质素
亚铁氰化物
材料科学
化学工程
电化学
循环伏安法
电泳沉积
吸附
木质素磺酸盐
氧化还原
无机化学
电极
化学
有机化学
纳米技术
涂层
物理化学
工程类
作者
Teofil Jesionowski,Łukasz Kłapiszewski,Grzegorz Milczarek
标识
DOI:10.1016/j.matchemphys.2014.06.058
摘要
Synthesis and characterisation of silica/lignin materials is described. Silica was synthesised by the modified Stöber method and its surface was functionalised with aminosilane. The organic matrix was the activated Kraft lignin (KL). The materials obtained were subjected to thorough characterisation (physicochemical, dispersive, morphological and electrochemical) by the NIBS, SEM, FT–IR, and XPS methods. Results of the characterisation permitted evaluation of the application possibilities of the products and the choice of the best ones for specific applications. Because of high negative ionic charge the material particles could be effectively deposited on positively polarised glassy carbon electrode by electrophoretic deposition. The silica/lignin modified electrode showed enhanced charge transfer resistance for anionic redox probe (ferrocyanide/ferricyanide couple) and an enhanced capability to the adsorption of silver cations. The latter property could be exploited in anodic striping voltammetry of silver.
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