石墨烯
材料科学
氧化物
化学工程
钴
阳极
层状结构
堆积
介孔材料
复合数
氧化钴
卟啉
电极
纳米技术
化学
复合材料
催化作用
有机化学
冶金
物理化学
工程类
作者
Yang Han,Zhoujia Liu,Fenfen Zheng,Yixuan Bai,Zhiqian Zhang,Yong Li,Wenhui Xiong,Junhao Zhang,Aihua Yuan
标识
DOI:10.1016/j.jallcom.2021.160531
摘要
In this study, a novel flower-like Co-TCPP MOF/rGO composite has been successfully synthesized by combining cobalt meso-tetrakis(4-carboxyphenyl) porphyrin (Co-TCPP MOF) and reduced graphene oxide (rGO) via a simple one-pot solvothermal method. The introduction of rGO not only reduces the stacking of MOF effectively, but also facilitates the formation of a continuous conductive network composed of entangled graphene and Co-TCPP MOF in favor of rapid electron transport. More importantly, the ultrathin lamellar structure of Co-TCPP MOF/rGO composite nanosheets could expose more active sites, reduce the diffusion distance of Li+ to the internal electroactive sites, and improve the overall electrical conductivity of the electrode due to their sufficient contact with carbon. When evaluated as anode materials for lithium-ion batteries, the flower-like Co-TCPP MOF/(15 wt%)rGO composite electrode delivers a specific capacity of 1050 mAh g−1 at 100 mA g−1 after 100 cycles. A specific capacity of 650 mAh g−1 can be remained after 300 cycles even at 1000 mA g−1. The superior performance of the Co-TCPP MOF/(15 wt%)rGO composite electrode could be attributed to the introduction of rGO, which prevents the stacking growth of Co-TCPP MOF crystals along the horizontal direction and improves the electrical conductivity.
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