Dynamic reconfigurable metamaterials for coordinated heat and charge transport

热电效应 掩蔽 热电发电机 超材料 热电材料 热电冷却 能量转换 塞贝克系数 材料科学 热的 热能 计算机科学 联轴节(管道) 拓扑(电路) 瞬态(计算机编程) 转化(遗传学) 电荷(物理) 工作(物理) 电势能 热流密度 物理 工程物理 能量收集 光电子学 坐标系 电子工程 热导率 能量流
作者
Min Lei,Fu-Bao Yang,Jiping Huang,Jun Wang
出处
期刊:Applied physics reviews [American Institute of Physics]
卷期号:13 (3)
标识
DOI:10.1063/5.0331285
摘要

Coordinated control of coupled heat and charge transport is fundamental to advanced thermoelectric energy conversion and management. Existing thermoelectric metamaterials are largely limited to static or steady-state functionalities. While spatiotemporal modulation has enabled dynamic regulation of single diffusion fields, extending such control to coupled thermoelectric systems remains challenging due to the intrinsic coupling via the Seebeck and Peltier effects and the vastly different thermal and electrical timescales. A unified theoretical framework for designing physically consistent, dynamically reconfigurable thermoelectric devices under transient conditions is lacking. Here, we establish a time-dependent transformation theory for coupled thermoelectric fields. We prove that the governing equations retain form invariance under coordinate transformations even when material parameters vary in space and time, and derive transformation rules for thermal conductivity, electrical conductivity, heat capacity, and the Seebeck coefficient. This enables the systematic design of dynamic thermoelectric functionalities through spacetime-dependent coordinate mappings. We numerically demonstrate three representative functionalities—cloaking, concentration, and rotation—in which heat flux and electric current are manipulated simultaneously without disturbing external fields. Furthermore, we design a time-adjustable thermoelectric cloak-concentrator by introducing a time-dependent virtual radius. For experimental realization, we propose a rotatable checkerboard structure based on effective-medium theory that exhibits periodic switching between cloaking and concentrating modes using conventional metals. This work provides a unified framework for designing dynamically reconfigurable thermoelectric devices, transcending the functionality-fixed limitation of conventional metamaterials. The theory is generalizable to other coupled diffusion processes, opening avenues for adaptive energy routing, intelligent thermal management, and spatiotemporal information processing.

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