Polarized Remote Inversion of the Refractive Index of Marine Spilled Oil From PARASOL Images Under Sunglint

The ability to detect oil spills remotely is important in marine environmental monitoring. The optical polarization remote sensing has the unique advantage of inversion of refractive index of spilled oils which is the key parameter for calculation of sunglint reflectance. Compared to nonpolarization optical image, the degree of linear polarization (DOLP) of spilled oil's sunglint depends on the refractive index and viewing angles but not on the surface roughness. Accurate correction of sunglint reflectance can promote optical estimation of spilled oils. In this article, a polarized optical model was used to calculate equivalent refractive index of Deepwater Horizon (DWH) spilled oils using space-borne Polarization and Anisotropy of Reflectances for Atmospheric Sciences coupled with Observations from a Lidar (PARASOL) images covering Gulf of Mexico (GOM) in 2010. When the angle (θm) between the direction of the flat surface specular reflection and that of observation is less than 20°, the PARASOL-derived and modeled DOLPs agree well, and the atmospheric polarization effects can be neglected. The equivalent refractive index of the spilled oil area, which implies the relative proportions of seawater and spilled oil in each pixel, could be estimated using polarized remote sensing under sunglint. Furthermore, if the relationship between the equivalent refractive index and remote sensing reflectance (Rrs) of spilled oils in the remote sensing images can be given, it might be used to correct the sunglint effect on various spilled oils, thereby leading to an improvement for optical quantifying spilled oil volume.