量子产额
化学计量学
化学
碳纤维
柠檬酸
无机化学
水热合成
产量(工程)
氮气
量子点
材料科学
荧光
化学工程
热液循环
纳米技术
有机化学
复合材料
冶金
工程类
物理
复合数
量子力学
作者
Shawninder Chahal,Nariman Yousefi,Nathalie Tufenkji
出处
期刊:ACS Sustainable Chemistry & Engineering
[American Chemical Society]
日期:2020-03-20
卷期号:8 (14): 5566-5575
被引量:78
标识
DOI:10.1021/acssuschemeng.9b07463
摘要
Despite a growing interest in carbon dots (CDs), notably for their potential as a more sustainable, less toxic alternative to inorganic quantum dots, the critical factors affecting their physical, chemical, and optical properties are relatively unknown, limiting their widespread use. Herein, a one-pot hydrothermal method was used to synthesize CDs from citric acid and phenylalanine. CDs were synthesized over a range of reactant ratios, from pure citric acid to pure phenylalanine and seven mixed ratios in between, achieving a quantum yield (QY) as high as 65% with a peak excitation/emission of 350/413 nm. The goal was to determine the role of stoichiometry on the chemical and structural composition of CDs, particularly its impact on nitrogen doping, and in turn its effect on QY. We showed that a wide range of reactant ratios tend toward reacting in a stoichiometric 2:1 molar ratio of phenylalanine to citric acid whereby the resulting CDs have similar chemical composition and QY. Using this ratio may lead to a more efficient and sustainable mass production process by reducing and reusing reactant waste. The QY of the CDs was found to be more dependent on the oxygen-to-carbon ratio and the relative amount of carboxyl oxygen in the CD than it was on the nitrogen-to-carbon ratio. The resulting CDs also showed Fe3+ sensing capabilities through static fluorescence quenching with a limit of detection of 3.5 μM. This study provides new insights which may be useful for the optimization of the green synthesis of CDs for more widespread applications.
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