TiO2 nanotube arrays-based photoelectrocatalyst: Tri-Doping engineering and carbon coating engineering boosting visible activity, and stable hydrogen evolution

The integration of non-metallic doping and carbon coating for TiO2-based photoelectrocatalysts can be recognized as a promising strategy to enhance their hydrogen production performance. To this end, this study explored the carbon coating engineering to induce stable multi-element doping with an aim to develop high-performance TiO2 nanotube array-based photoelectrocatalysts. The resulting structures consisted of carbon–nitrogen-sulfur-tri-doped TiO2 nanotube arrays with a nitrogen-sulfur-codoped carbon coating (CNS-TNTA/NSC). The fabrication process involved a one-step, low-cost strategy of the carbon-coated tridoped reaction confined in vacuum space, utilizing polymer thiourea sealed in a controlled environment. Compared the photocurrent density of CNS-TNTA/NSC with pristine TNTA, the photocurrent enhancement of approximately 18.3-fold under simulated sunlight and a remarkable increase of 32.8-fold under simulated visible light conditions. The enhanced photocatalytic activity under visible light was ascribed to two factors: First, C, N, and S tri-doping and Ti3+ created a diverse array of impurity energy levels within the band gap, which synergistically narrowed the band gap and further enhanced response to the visible light range. Second, the presence of a carbon coating shell doped with N and S can greatly promote electron transfer and efficient electron-hole pair separation. This study could provide significant insights concerning the design of sophisticated photoanodes.