Development of Activated Carbon Textiles Produced from Jute and Cotton Wastes for Electromagnetic Shielding Applications

材料科学 活性炭 碳化 废物管理 硫酸 热解 织物 复合材料 制浆造纸工业 化学 有机化学 冶金 吸附 扫描电子显微镜 工程类
作者
Sema Sert,Deniz Duran Kaya,Ayşegül Körlü
出处
期刊:Fibers [Multidisciplinary Digital Publishing Institute]
卷期号:11 (12): 110-110 被引量:6
标识
DOI:10.3390/fib11120110
摘要

Increasing amounts of waste resulting from over-consumption carry substantial risks for human and environmental health, and disposing of this waste requires enormous amounts of energy. As a result, waste-to-wealth and circular economy approaches have gained attention in both academia and the commercial sector in recent years. Accordingly, this study aims to develop electromagnetic shielding materials by converting non-conductive waste textiles into conductive value-added product and porous fabrics by carbonizing the structure itself rather than by adding any conductive particles. To this end, the novel contribution of the present study is that waste textiles were converted into activated carbon in a shorter time and without compromising the integrity of the fibrous network via microwave pyrolysis without inert gas. Sulfuric acid was used as a dehydration and activation agent, suppressing the release of volatile organic substances and eliminating greenhouse gas emissions. This approach also increased product yield and reduced energy consumption and sample shrinkage. The structures of the activated carbon textile showed EMI shielding within 20–30 dB (99.9% attenuation) in the 1–6 GHz frequency range. The maximum SSE/t value of 950.71 dB·cm2·g−1 was obtained with the microwave post-treated activated carbon textile. Micropores were dominant characteristics of these materials, and pore diameters increased with increased acid concentration. The maximum surface area of 383.92 m2/g was obtained with 8% acid. Ultrasound treatment reduced water-energy consumption and cost. Only 5 min of microwave post-treatment increased textile conductivity and thermal stability and contributed positively to electromagnetic shielding.
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