Abundant Dislocation Layered Double Hydroxides Synthesis by Molten Salt with Bound Water Boosting Oxygen Evolution

Abstract Optimizing the adsorption free energy and promoting the active phase transition to further enhance the oxygen evolution reaction (OER) activity remain significant challenges. The adsorption free energy can be optimized by modulating the electronic structure and adjusting the crystal configuration. Meanwhile, the transformation of the active phase can be promoted by introducing strain energy. The theoretical calculations are conducted to verify the rational envisage. However, it is still a great obstacle to introducing strain into the electrocatalysts and avoiding destruction. The stress field caused by dislocation can realize both of the above. Hence, the molten salt with the bound water method is proposed and the abundant dislocation layered double hydroxides (D‐NiFe LDH) are constructed. The in situ characterizations further verify the dislocations significantly affect the generation of the active phase and the state of electronic structure. Consequently, the D‐NiFe LDH exhibits outstanding OER activity and obtains 10 mA cm −2 , only requiring 199 mV overpotential with fabulous stability (100 mA cm −2 more than 24 h). The work paves a new avenue for the rational introduction dislocations to optimize the crystal configuration and boost the active phase formation, significantly enhancing the OER performance.