Reactivity enhancement of a diphosphene by reversible N-heterocyclic carbene coordination
作者
Debabrata Dhara,Pankaj Kalita,Subhadip Mondal,Ramakirushnan Suriya Narayanan,Kaustubh R. Mote,Volker Hüch,Michael Zimmer,Cem B. Yildiz,David Scheschkewitz,Vadapalli Chandrasekhar,Anukul Jana
出处
期刊:Chemical Science [Royal Society of Chemistry] 日期:2018-01-01卷期号:9 (18): 4235-4243被引量:36
The reversible coordination of an N-heterocyclic carbene (NHC) enhances the reactivity of a diphosphene towards hydrolysis and transfer hydrogenation. The hydrolysis is catalytic in NHC.