(N‐Phosphinoamidinate)cobalt‐Catalyzed Hydroboration: Alkene Isomerization Affords Terminal Selectivity

Abstract Herein we establish the utility of a three‐coordinate ( N ‐phosphinoamidinate)cobalt(amido) pre‐catalyst that is capable of effecting challenging alkene isomerization/hydroboration processes at room temperature, leading to the selective terminal addition of the boron group.