超级电容器
材料科学
电解质
层状双氢氧化物
盐(化学)
阴极
阳极
电容
化学工程
功率密度
聚吡咯
水溶液
电流密度
化学
电化学
功率(物理)
电极
氢氧化物
物理化学
工程类
物理
量子力学
作者
Xijuan Li,XuKun Wang,Lei Guo,Xinyi Sui,Qingfeng Wu,Xinge Wang,Xueliang Lv,Erqing Xie,Zhengxing Zhang
标识
DOI:10.1016/j.cej.2022.139140
摘要
Layered double hydroxides (LDHs) have been considered promising electrode materials in micro-supercapacitors (MSCs) for their high theoretical capacity, adjustable composition, designable function, and facile synthesis. However, the low energy density and disappointing cycle stability are still the main problems. Herein, water-in-salt (WIS) aqueous electrolyte and PPy coating of metal hydroxides are applied to broaden the working potential and stabilize the structure during the charge/discharge process. The asymmetric MSCs with PPy@NiCo-LDH@ITO NWs as the cathode, PPy@FeOOH@ITO NWs as the anode, and WIS electrolyte as the electrolyte have been assembled. The hybrid MSCs perform a high voltage window of 2.5 V, a high areal capacitance of 63.04 mF cm−2 at 0.4 mA cm−2, a maximum volumetric energy density of 32.2 mWh cm−3 (54.7 μWh cm−2) at a power density of 294.1 mW cm−3 (0.5 mW cm−2), and remarkable cyclic stability with 85 % capacitance retention after 8000 cycles at 5 mA cm−2. Remarkably, the series–parallel lighting tests demonstrate good device conformance. These results suggest a new perspective for applying WIS electrolytes for high-performance LDH-based MSCs.
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