超级电容器
材料科学
尼亚尔
层状双氢氧化物
微观结构
化学工程
氢氧化物
电解质
兴奋剂
钴
电极
纳米技术
电容
复合材料
化学
冶金
光电子学
合金
金属间化合物
物理化学
工程类
作者
Xiaoqiu Yue,Yingxia Dong,Heng Cao,Xiujuan Wei,Qiaoji Zheng,Wei Sun,Dunmin Lin
标识
DOI:10.1016/j.jcis.2022.10.033
摘要
Layered double hydroxides (LDHs) with high theoretical capacity have broad prospectsin energy storage applications. However, their slow charge transfer kinetics and easy agglomerate hinder their applications in high-performance supercapacitors. Herein, Co2+-doped nickel aluminum layered double hydroxides (NiAl-LDH-Co2+-x, x = 0, 0.3, 0.6, 0.9, 1.2, 1.5) have been designed and prepared by a convenient hydrothermal process. The multicomponent layer structure formed by cobalt doping facilitates sufficient penetration of the electrolyte and accelerates the charge transfer kinetics. Furthermore, the more open layer spacing and electronic interactions induced by Co2+ doping are conducive to accelerating ion de-intercalation, thereby further improving the kinetic behavior of charge storage. Benefiting from the unique microstructure and Co2+ doping effect, the prepared NiAl-LDH-Co2+-0.9 provides a superior specific capacity of 985 C g-1 at 1 A g-1. In addition, the assembled hybrid supercapacitor with the NiAl-LDH-Co2+-0.9 as the positive electrode provides a remarkable energy density of 22.51 Wh kg-1 at a power density of 800 W kg-1 and exhibits an excellent cycle life with 80 % capacity retention after 20,000 cycles. This study demonstrates the great potential of efficient microstructure design and doping strategy in enhancing the charge storage of electrode materials.
科研通智能强力驱动
Strongly Powered by AbleSci AI