A Theory‐Driven Moderation Strategy for Electrolyte Design Unlocks Stable Aqueous Zinc Deposition

coordination structure and interface stability. As a result, 1,6-hexanediol, exhibited a set of balanced and non-extremum molecular parameters, significantly enhanced the reversibility of zinc deposition/stripping, delivered the best electrochemical performance that extending the cycling lifespan to 2 600 h, which is consistent with the Sabatier principle. This study provides a new theoretical perspective for the rational screen of electrolyte additives and highlights the importance of expanding the selection criteria for optimizing interfacial stability.