Amphiphilic Palladium NHC-complexes with Chelating Bis-NHC Ligands Based on Imidazole-4,5-dicarboxylic Acid: Synthesis and Catalysis in water.

Efficient catalytic systems for various organic transformations in green solvents, especially water, are in great demand. Catalytically active bis-NHC complexes of palladium(II) based on imidazole-4,5-dicarboxylic acid with different lipophilicities were obtained. The synthesis of imidazolium salts was complicated by the formation of side products of nucleophilic substitution by iodide ions in the Menshutkin reaction involving alkyl iodides, which was successfully resolved by using alkyl tosylates. The synthesis of bis-NHC complexes of palladium(II) was carried out