立体中心
对映选择合成
吲哚试验
化学
组合化学
四级碳
反应条件
催化作用
有机化学
作者
Guang‐Jian Mei,Xiwen Tang,Yildiz Tasdan,Yixin Lü
标识
DOI:10.1002/anie.201911686
摘要
Abstract The enantioselective dearomatization of indoles by an organocatalytic (3+2) reaction has been established. The reaction makes use of simple indole derivatives as substrates, and employs azoalkenes reaction partners. A wide range of pyrroloindolines containing an all‐carbon quaternary stereogenic center were readily prepared in high yields and with excellent enantioselectivities.
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