Advances to High‐Performance Black‐Phase FAPbI3 Perovskite for Efficient and Stable Photovoltaics

Formamidinium lead iodide (FAPbI 3 )‐based perovskites have become one of the most promising candidate materials for high efficiency and thermally stable perovskite solar cells due to their outstanding optoelectrical properties and high thermal stability. However, the phase degradation of black FAPbI 3 perovskite phase to yellow nonperovskite phase at ambient conditions restricts the long‐term stability of FAPbI 3 perovskite solar cells. Such phase transition can be affected by various conditions especially under humidity and thermal stress. To address the phase instability issue, tremendous research efforts have been devoted to crystallizing high‐quality black phase and refraining the photoinactive δ‐phase formation. Herein, first, these research efforts are summarized for the deposition of FAPbI 3 perovskite film and the stabilization of pure α‐FAPbI 3 perovskite, then the FAPbI 3 structural features and phase transformation behavior are discussed. The corresponding strategies for maintaining black phase and enhancing optical properties of FAPbI 3 perovskite is also concluded. Second, the latest progress and achievement of stabilizing black‐phase FAPbI 3 are discussed through various methods including additives, doping, and alloying, interfacial engineering, etc. Finally, the future research directions and strategies to achieve high efficiency and stable FAPbI 3 ‐based perovskite solar cells are described.