Recent advances in electrocatalytic nitrite reduction

Electrocatalytic nitrite reduction is of great significance for wastewater treatment and value-added chemicals synthesis. This review highlights the latest progress in electrochemical nitrite reduction to produce two types of products, including gaseous products (NO, N₂O, N₂) and liquid products (NH₂OH and NH₄⁺). The heterogeneous and homogeneous catalysts used in the corresponding reduction processes are introduced, with emphasis on the product selectivity regulation and reaction mechanism understanding. Finally, the challenges and opportunities in this field are analyzed as well. This review can provide guidelines for designing electrochemical systems with high efficiency and specificity for nitrite reduction.