A structural, spectroscopic and theoretical study of an o-vanillin Schiff base derivative involved in enol-imine and keto-amine tautomerism

The potassium salt of the Schiff base derived from o -vanillin and taurine is involved in enol-imine (I) and keto-amine (II) tautomerism. Both tautomeric forms coexist in the crystal and they are stabilized by strong O–H⋯N and O⋯H–N intramolecular hydrogen bonds.