超级电容器
材料科学
电容
电极
功率密度
无定形固体
微观结构
单斜晶系
化学工程
电流密度
相(物质)
纳米技术
降水
复合材料
化学
结晶学
晶体结构
物理化学
有机化学
功率(物理)
气象学
工程类
物理
量子力学
作者
Mao‐Cheng Liu,Jiajia Li,Wei Han,Long Kang
标识
DOI:10.1016/j.jechem.2016.03.002
摘要
Flower-like Ni3P2O8 and flower-like Fe3P2O8·8H2O have been successfully synthesized by a simple chemical precipitation method. X-ray diffraction (XRD) patterns reveal an amorphous phase formation of nickel phosphate (Ni3P2O8) and pure monoclinic phase of Fe3P2O8·8H2O. The novel flower-like Ni3P2O8 and flower-like Fe3P2O8·8H2O when used for supercapacitor electrode materials exhibit a high specific capacitance (Cm) of 1464 F/g and 200 F/g at a current density of 0.5 A/g, respectively. Eventually, an asymmetric supercapacitor is fabricated using Ni3P2O8 as positive electrode and Fe3P2O8·8H2O as negative electrode. A high specific capacitance of 94 F/g is achieved in the high-voltage region of 0 ∼1.6 V, and a large energy density of 32.6 Wh/kg is delivered at power density of 420 W/kg. The findings demonstrate the important and great potential of developing metal phosphate based materials for supercapacitors.
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