异质结
材料科学
三元运算
光催化
化学工程
吸附
载流子
碳纤维
能量转换效率
光电子学
催化作用
物理化学
有机化学
复合数
复合材料
工程类
计算机科学
化学
程序设计语言
作者
Shuangchao Zhao,Keyan Li,Jiaming Wu,Jiaxing Zhang,Xiangyang Li,Xinwen Guo,Chunshan Song
标识
DOI:10.1021/acsami.1c16096
摘要
Realizing high-efficiency solar-driven CO2 reduction to chemicals and fuels requires high-performance photocatalysts with high utilization efficiency of solar light, efficient charge separation and transfer, and robust adsorption capacity for CO2. In this work, a tubular In2O3-C/CdIn2S4 (IOC/CIS) ternary heterojunction with an intimate interfacial contact was fabricated by pyrolysis of In-MIL-68 and subsequent solvothermal synthesis of CdIn2S4. The construction of a heterojunction promotes the separation and transfer efficiency of photogenerated carriers. The introduction of carbon not only accelerates the interfacial charge migration but also enhances light absorption and CO2 adsorption. The resulting 5IOC/CIS sample presents a remarkably improved photocatalytic CO2 reduction activity with a CO generation rate of 2432 μmol g-1 h-1, much higher than that of the In2O3/CdIn2S4 (IO/CIS) heterojunction (1906 μmol g-1 h-1). Furthermore, the type II charge transfer mechanism of the heterojunction was confirmed by the electron paramagnetic resonance characterization. This work provides new insight into the design and preparation of a highly efficient hollow heterojunction for photocatalytic applications.
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