材料科学                        
                
                                
                        
                            量子点                        
                
                                
                        
                            钙钛矿(结构)                        
                
                                
                        
                            光电子学                        
                
                                
                        
                            二极管                        
                
                                
                        
                            发光二极管                        
                
                                
                        
                            纳米技术                        
                
                                
                        
                            化学                        
                
                                
                        
                            结晶学                        
                
                        
                    
            作者
            
                Hung‐Chia Wang,Zhen Bao,Hsinyu Tsai,An‐Cih Tang,Ru‐Shi Liu            
         
                    
            出处
            
                                    期刊:Small
                                                         [Wiley]
                                                        日期:2017-11-30
                                                        卷期号:14 (1)
                                                        被引量:314
                                 
         
        
    
            
            标识
            
                                    DOI:10.1002/smll.201702433
                                    
                                
                                 
         
        
                
            摘要
            
            Abstract Perovskite quantum dots (PQDs) attract significant interest in recent years because of their unique optical properties, such as tunable wavelength, narrow emission, and high photoluminescence quantum efficiency (PLQY). Recent studies report new types of formamidinium (FA) PbBr 3 PQDs, PQDs with organic–inorganic mixed cations, divalent cation doped colloidal CsPb 1− x M x Br 3 PQDs (M = Sn 2+ , Cd 2+ , Zn 2+ , Mn 2+ ) featuring partial cation exchange, and heterovalent cation doped into PQDs (Bi 3+ ). These PQD analogs open new possibilities for optoelectronic devices. For commercial applications in lighting and backlight displays, stability of PQDs requires further improvement to prevent their degradation by temperature, oxygen, moisture, and light. Oxygen and moisture‐facilitated ion migration may easily etch unstable PQDs. Easy ion migration may result in crystal growth, which lowers PLQY of PQDs. Surface coating and treatment are important procedures for overcoming such factors. In this study, new types of PQDs and a strategy of improving their stabilities are introduced. Finally, this paper discusses future applications of PQDs in light‐emitting diodes.
         
            
 
                 
                
                    
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