卤化物
快离子导体
电化学
电解质
材料科学
离子电导率
泥浆
制作
纳米技术
材料设计
电极
化学
无机化学
物理化学
复合材料
病理
医学
替代医学
作者
Hiram Kwak,Shuo Wang,Juhyoun Park,Yunsheng Liu,Kyu Tae Kim,Yeji Choi,Yifei Mo,Yoon Seok Jung
出处
期刊:ACS energy letters
[American Chemical Society]
日期:2022-04-26
卷期号:7 (5): 1776-1805
被引量:96
标识
DOI:10.1021/acsenergylett.2c00438
摘要
Recently, halide superionic conductors have emerged as promising solid electrolyte (SE) materials for all-solid-state batteries (ASSBs), owing to their inherent properties combining high Li+ conductivity, good chemical and electrochemical oxidation stabilities, and mechanical deformability, compared to sulfide or oxide SEs. In this Review, recent advances in halide Li+- and Na+-conducting SEs are comprehensively summarized. After introducing the ionic diffusion mechanism and related governing factors of the crystal structures, we discuss the design strategies, such as the substitution and synthesis protocols, of the halide materials for further improving their properties. We review theoretical and experimental results on electrochemical stabilities and compatibilities with electrode materials. Moreover, we offer a critical assessment of the challenges and issues associated with the development of practical ASSB applications, such as cost considerations, stabilities in atmospheric air, aqueous solutions, and slurry-processing, and the wet-slurry or dry fabrication of sheet-type electrodes (or SE membranes) for large-format ASSBs. Based on these discussions, we provide a perspective on the future research directions of halide SEs, emphasizing the need for expanding the materials space.
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