电泳剂
化学
组合化学
芳基
杂原子
电化学
烷基
有机化学
催化作用
物理化学
电极
作者
Yaowen Liu,Pengfei Li,Yanwei Wang,Youai Qiu
标识
DOI:10.1002/anie.202306679
摘要
Electrochemistry utilizes electrons as a potent, controllable, and traceless alternative to chemical oxidants or reductants, and typically offers a more sustainable option for achieving selective organic synthesis. Recently, the merger of electrochemistry with readily available electrophiles has been recognized as a viable and increasingly popular methodology for efficiently constructing challenging C-C and C-heteroatom bonds in a sustainable manner for complex organic molecules. In this mini-review, we have systematically summarized the most recent advances in electroreductive cross-electrophile coupling (eXEC) reactions during the last decade. Our focus has been on readily available electrophiles, including aryl and alkyl organic (pseudo)halides, as well as small molecules such as CO2 , SO2 , and D2 O.
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