生物传感器
傅里叶变换红外光谱
去壳
纳米材料
荧光
检出限
材料科学
离子键合
光谱学
化学
量子点
带隙
分析化学(期刊)
纳米技术
化学工程
光电子学
有机化学
色谱法
光学
物理
工程类
离子
量子力学
生物
植物
作者
Devadass Jessy Mercy,Venkatakrishnan Kiran,Anbazhagan Thirumalai,Karthick Harini,Koyeli Girigoswami,Agnishwar Girigoswami
标识
DOI:10.1016/j.rechem.2023.101219
摘要
Recently, the green method synthesized biosensors have been used for numerous environmental and biomedical applications, especially nanomaterials-based biosensors. Herein, novel, environmentally friendly, and water-soluble carbon quantum dots (CQDs) have been synthesized from the readily available green source (rice husk) without any ionic or covalent modifications via a one-pot synthesis method. The CQDs were characterized using UV-visible spectroscopy, and Fourier transform infrared spectroscopy, and their optical properties were determined. The stability of the synthesized CQDs was determined under the effect of pH, time, and temperature and on different excitation wavelengths. The band gap energy was calculated using Tauc’s equation with the energy of 3.2 eV, which indicated that the CQDs are fluorescent, and the linear range and association constant were determined by the Stern- Volmer relation and Bensi- Hildebrand equation, respectively. The photophysical studies indicated the strong fluorescence emission with excitation dependent behaviour and the CQDs relation with amoxicillin. Hence, in this study, the sensor producing remarkable sensitivity of antibiotics with a detection limit in the nM range was proposed.
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