Molecular Sieve Membrane: Supported Metal–Organic Framework with High Hydrogen Selectivity

Angewandte Chemie International EditionVolume 49, Issue 3 p. 548-551 Communication Molecular Sieve Membrane: Supported Metal–Organic Framework with High Hydrogen Selectivity† Yan-Shuo Li Prof. Dr., Yan-Shuo Li Prof. Dr. yanshuo.li@pci.uni-hannover.de Institute of Physical Chemistry and Electrochemistry and the Laboratory for Nano and Quantum Engineering (LNQE) in cooperation with the Center for Solid State Research and New Materials, Leibniz Universität Hannover, Callinstrasse 3 A, 30167 Hannover (Germany), Fax: (+49) 511-762-19121 State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Zhong-Shan Road 457, 116023 Dalian (China)Search for more papers by this authorFang-Yi Liang, Fang-Yi Liang Institute of Physical Chemistry and Electrochemistry and the Laboratory for Nano and Quantum Engineering (LNQE) in cooperation with the Center for Solid State Research and New Materials, Leibniz Universität Hannover, Callinstrasse 3 A, 30167 Hannover (Germany), Fax: (+49) 511-762-19121Search for more papers by this authorHelge Bux, Helge Bux Institute of Physical Chemistry and Electrochemistry and the Laboratory for Nano and Quantum Engineering (LNQE) in cooperation with the Center for Solid State Research and New Materials, Leibniz Universität Hannover, Callinstrasse 3 A, 30167 Hannover (Germany), Fax: (+49) 511-762-19121Search for more papers by this authorArmin Feldhoff, Armin Feldhoff Institute of Physical Chemistry and Electrochemistry and the Laboratory for Nano and Quantum Engineering (LNQE) in cooperation with the Center for Solid State Research and New Materials, Leibniz Universität Hannover, Callinstrasse 3 A, 30167 Hannover (Germany), Fax: (+49) 511-762-19121Search for more papers by this authorWei-Shen Yang Prof. Dr., Wei-Shen Yang Prof. Dr. State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Zhong-Shan Road 457, 116023 Dalian (China)Search for more papers by this authorJürgen Caro Prof. Dr., Jürgen Caro Prof. Dr. juergen.caro@pci.uni-hannover.de Institute of Physical Chemistry and Electrochemistry and the Laboratory for Nano and Quantum Engineering (LNQE) in cooperation with the Center for Solid State Research and New Materials, Leibniz Universität Hannover, Callinstrasse 3 A, 30167 Hannover (Germany), Fax: (+49) 511-762-19121Search for more papers by this author Yan-Shuo Li Prof. Dr., Yan-Shuo Li Prof. Dr. yanshuo.li@pci.uni-hannover.de Institute of Physical Chemistry and Electrochemistry and the Laboratory for Nano and Quantum Engineering (LNQE) in cooperation with the Center for Solid State Research and New Materials, Leibniz Universität Hannover, Callinstrasse 3 A, 30167 Hannover (Germany), Fax: (+49) 511-762-19121 State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Zhong-Shan Road 457, 116023 Dalian (China)Search for more papers by this authorFang-Yi Liang, Fang-Yi Liang Institute of Physical Chemistry and Electrochemistry and the Laboratory for Nano and Quantum Engineering (LNQE) in cooperation with the Center for Solid State Research and New Materials, Leibniz Universität Hannover, Callinstrasse 3 A, 30167 Hannover (Germany), Fax: (+49) 511-762-19121Search for more papers by this authorHelge Bux, Helge Bux Institute of Physical Chemistry and Electrochemistry and the Laboratory for Nano and Quantum Engineering (LNQE) in cooperation with the Center for Solid State Research and New Materials, Leibniz Universität Hannover, Callinstrasse 3 A, 30167 Hannover (Germany), Fax: (+49) 511-762-19121Search for more papers by this authorArmin Feldhoff, Armin Feldhoff Institute of Physical Chemistry and Electrochemistry and the Laboratory for Nano and Quantum Engineering (LNQE) in cooperation with the Center for Solid State Research and New Materials, Leibniz Universität Hannover, Callinstrasse 3 A, 30167 Hannover (Germany), Fax: (+49) 511-762-19121Search for more papers by this authorWei-Shen Yang Prof. Dr., Wei-Shen Yang Prof. Dr. State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Zhong-Shan Road 457, 116023 Dalian (China)Search for more papers by this authorJürgen Caro Prof. Dr., Jürgen Caro Prof. Dr. juergen.caro@pci.uni-hannover.de Institute of Physical Chemistry and Electrochemistry and the Laboratory for Nano and Quantum Engineering (LNQE) in cooperation with the Center for Solid State Research and New Materials, Leibniz Universität Hannover, Callinstrasse 3 A, 30167 Hannover (Germany), Fax: (+49) 511-762-19121Search for more papers by this author First published: 07 January 2010 https://doi.org/10.1002/anie.200905645Citations: 502 † Y.-S. Li is grateful for the financial support from the Alexander von Humboldt Foundation. DFG Priority Program 1362 "Porous Metal–Organic Frameworks" is acknowledged for financial support. The authors thank F. Steinbach for support in electron microscopy and K. Efimov for TGA measurements. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Molecular strainer: An ultramicroporous zeolitic imidazolate framework (ZIF-7) was tested for its gas-separation properties in membrane applications. ZIF-7 was appended to an asymmetric alumina support using microwave-assisted seeded growth, and the resulting ZIF-7 membrane exhibits high H2 selectivity as a molecular sieve and has excellent thermal stability. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description anie_200905645_sm_miscellaneous_information.pdf642.8 KB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume49, Issue3January 12, 2010Pages 548-551 RelatedInformation