化学
区域选择性
位阻效应
MNDO公司
肌醇
药物化学
立体化学
有机化学
分子
催化作用
受体
生物化学
作者
Cai Yuan,Hongbin Zhai,Shusen Li
标识
DOI:10.1002/cjoc.19960140314
摘要
Abstract During the etherification of 1,2‐ O ‐isopropylidene‐4,6‐di‐ O ‐benzyl myo ‐inositol, the specific regioselectivity on 3‐ or 5‐hydroxyl group was showed to be determined by the nature of the O‐ alkylating agents used. As demonstrated by MM and MNDO calculation, the regioselectivity of the reaction mentioned can be rationalized by steric and/or electronic effect.
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