烯烃
亲核细胞
催化作用
芳基
联轴节(管道)
化学
组合化学
原位
有机化学
材料科学
烷基
冶金
作者
Kevin B. Smith,Kaitlyn M. Logan,Wei You,M. Kevin Brown
标识
DOI:10.1002/chem.201404310
摘要
A synergistic Pd/Cu system for the coupling of alkenes, (Bpin)2 (pin = pinacolate), and aryl/vinyl bromides is disclosed. This method allows for the catalytic generation of secondary Csp(3)-Cu nucleophiles in situ and subsequent Pd-catalyzed cross-coupling.
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