层流
氢
当量比
层流火焰速度
刘易斯数
燃烧
热力学
摩尔分数
二甲醚
体积分数
化学
预混火焰
材料科学
有机化学
物理化学
甲醇
物理
燃烧室
作者
Huibin Yu,Erjiang Hu,Yu Cheng,Ke Yang,Xinyi Zhang,Zuohua Huang
出处
期刊:Energy & Fuels
[American Chemical Society]
日期:2015-06-12
卷期号:29 (7): 4567-4575
被引量:50
标识
DOI:10.1021/acs.energyfuels.5b00501
摘要
Laminar flame speeds of premixed dimethyl ether/hydrogen/air flames were measured in a constant volume bomb at different temperatures, equivalence ratios, and hydrogen blending ratios. Results reveal that laminar flame speeds increase with an increased hydrogen blending ratio and initial temperature. The Wang model and Zhao model both perform well in predicting laminar flame speeds of the blends. Furthermore, three different models for an effective Lewis number are validated, and the volume-fraction-weighted model performs well in predicting the Markstein length. The effects of hydrogen addition on the flame speed and Markstein length of fuel blends are systematically studied. The chemical kinetic effect induced by hydrogen addition plays a dominant role in increasing the laminar flame speed in comparison to thermal and diffusive effects. In addition, there exists a critical equivalence ratio in the trend of the Markstein length. At the equivalence ratio less than the critical equivalence ratio, the Markstein length decreases with increased hydrogen fraction, indicating that the addition of hydrogen enhances the diffusional thermal instability of the blends. While at the equivalence ratio larger than the critical equivalence ratio, the Markstein length increases with the increase of the hydrogen mole fraction. Finally, the combined parameter [Ze(Le −1)] can reflect the trend of Lb, which varies with the hydrogen blending ratio.
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