材料科学
阳极
锂(药物)
电化学
结晶度
金属间化合物
纳米尺度
化学工程
微观结构
粒径
透射电子显微镜
纳米颗粒
粒子(生态学)
锂离子电池
分散性
离子
纳米技术
合金
冶金
物理化学
化学
复合材料
电池(电)
电极
有机化学
高分子化学
内分泌学
海洋学
工程类
功率(物理)
医学
物理
量子力学
地质学
作者
C.Q. Zhang,Jiangping Tu,Xu Huang,Y.F. Yuan,Shuaifeng Wang,F. Mao
标识
DOI:10.1016/j.jallcom.2007.03.039
摘要
Nanoscale FeSn2 particles were prepared by chemical reduction process and solvothermal method and studied as anode materials for lithium ion batteries. The microstructure of FeSn2 was characterized by means of X-ray diffraction (XRD) and transmission electron microscopy (TEM). The FeSn2 powder prepared by chemical reduction process presented quasi-spherical morphology with aggregation, and the particle were 30–70 nm in sizes. The powder prepared by solvothermal process was nearly monodisperse nanospheres, and the particle size was 80 nm with narrow distribution. The electrochemical properties of the FeSn2 anodes were measured by galvanostatic charge–discharge tests and cyclic voltammetric analysis (CV). The FeSn2 intermetallic compound synthesized by solvothermal method showed lower initial discharge capacity and better cyclability than that prepared by chemical reduction process due to the better crystallinity. The nanoscale FeSn2 powders both delivered a high reversible discharge capacity (500 mAh g−1).
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