化学
支柱
平面的
手性(物理)
金属有机骨架
金属
离解(化学)
甲基橙
组合化学
结晶学
立体化学
有机化学
催化作用
光催化
物理
计算机图形学(图像)
工程类
结构工程
吸附
量子力学
手征对称破缺
计算机科学
Nambu–Jona Lasinio模型
夸克
作者
Nathan L. Strutt,David Fairen‐Jimenez,Julien Iehl,Marianne B. Lalonde,Randall Q. Snurr,Omar K. Farha,Joseph T. Hupp,J. Fraser Stoddart
摘要
An efficient synthetic route to an A1/A2-difunctionalized pillar[5]arene containing resolvable planar chirality has been developed and the arene employed as a strut in the synthesis of P5A-MOF-1, which has been demonstrated by X-ray powder diffraction analysis--supported by modeling--to be isoreticular with MOF-5. This metal-organic framework has an active domain that expresses good and selective uptake of neutral and positively charged electron-poor aromatic guests, which effect color changes of the cubic crystals from faint yellow to deep orange, arising from charge transfer between the guests and active domain of P5A-MOF-1.
科研通智能强力驱动
Strongly Powered by AbleSci AI