Copper-mediated thiolation of carbazole derivatives and related N-heterocycle compounds

Cu-mediated direct thiolation of carbazole derivatives with disulfides via C–H bond cleavage to give diaryl and alkyl aryl sulfides which easily extends to the synthesis of thioethers with a benzo[h]quinolone, 2-phenylquinoline or indole moiety in satisfactory yields.