高氯酸盐
化学
结晶学
配体(生物化学)
离子
氢键
Atom(片上系统)
立体化学
分子
受体
有机化学
计算机科学
生物化学
嵌入式系统
标识
DOI:10.1107/s1600536809048429
摘要
In the title three-dimensional heterometallic complex, {[AgEr(C6H4NO2)2(C2H3O2)(H2O)]ClO4}n, the eight-coordinate ErIII ion adopts a distorted bicapped trigonal-prismatic geometry, being coordinated by four O atoms from four different isonicotinate ligands, three O atoms from two different acetate ligands and one O atom of the water molecule. The two-coordinate AgI ion is surrounded by two N atoms from two different isonicotinate anions in a slightly bent configuration. These building blocks are connected by bridging isonicotinate and acetate ligands, generating a three-dimensional network. Ths structure is consolidated by O—H⋯O hydrogen bonding between the coordinated water molecule and a carboxylate group of the acetate ligand. The perchlorate anion is disordered over two sites with site-occupancy factors of 0.526 (13) and 0.474 (13), while the methyl group of the acetate ligand is equally disordered over two sites.
科研通智能强力驱动
Strongly Powered by AbleSci AI