Interpenetrating Liquid-Crystal Polyurethane/Polyacrylate Elastomer with Ultrastrong Mechanical Property

Liquid-crystal elastomer (LCE) materials, which have been developed and investigated for 4 decades, still lack real industrial applications. The fundamental obstacle is the modest force of LCEs generated in the LC-to-isotropic phase transition process, which is the most important actuation moment. Here, we report an interpenetrating liquid-crystal polyurethane/polyacrylate elastomer material, consisting of one main-chain polyurethane LCE and another liquid-crystal polyacrylate thermoset network, which are simultaneously polymerized. This two-way shape memory material can reversibly shrink/expand under thermal stimulus and show ultrastrong actuation-mechanics properties. With a maximum shrinkage ratio of 86% at 140 °C, which is beyond the LC-to-isotropic phase transition, its actuation blocking stress, actuation work capacity, breaking strength, and elastic modulus reach 2.53 MPa, 1267.7 kJ/m³, 7.9 MPa, and 10.4 MPa, respectively. Such LCE material can lift up a load 30 000 times heavier than its own weight. We hope the outstanding mechanical properties of this interpenetrating polymer network-LCE material would pave the way for real industrial utilizations of LCE-based soft actuators.