涂层
材料科学
硫黄
兴奋剂
膜
碳纤维
锂(药物)
氮气
锂硫电池
化学工程
复合材料
纳米技术
电化学
电极
化学
光电子学
冶金
复合数
有机化学
工程类
物理化学
内分泌学
医学
生物化学
作者
Kairu Han,Ting Wang,Na Zhang,Weimin Zhang,Wenqing Ge,Gang Xie,Lipeng Zhang,Tiezhu Zhang
标识
DOI:10.1016/j.electacta.2020.137232
摘要
Exploiting effective protocols to suppress the lithium polysulfide shuttling effect is critical to achieve a long life for lithium–sulfur (Li–S) batteries. Here we demonstrate a laminated separator which was obtained by coating a layer of tubular nitrogen doped carbon fibre (TNCF) on PP/PE/PP separator with an expect to alleviate such a problem. The hollow structured one-dimensional TNCF was obtained by pyrolyzing the tubular polypyrrole (PPy) which was synthesized through an auto-degradable template method. And the laminated separator was prepared by a simple vacuum-assisted filter method. Due to enhancement of the electrical conductivity and the chemisorption with lithium polysulfides, we observed that the rate performance and the cyclability of the Li–S battery were remarkably enhanced when the TNCF separator was used. The capacity decay rate were determined to be 0.13% and 0.33% per cycle upon 200 cycles at 0.5 C for the Li–S batteries with the TNCF coated and the un-coated separators, respectively. That present the TNCF coated separator a promising high performance separator for long-life Li–S batteries.
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